Journal
ORGANIC LETTERS
Volume 11, Issue 3, Pages 681-684Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8027412
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Funding
- Canada Research Chair Program
- Natural Sciences and Engineering Research Council of Canada
- Canada Foundation for Innovation
- Merck Frosst Centre for Therapeutic Research
- Fonds de recherche sur la nature et les technologies
- Universite Laval
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An addition/elimination reaction of organolithium reagents to silylated beta,beta-difluorostyrene derivatives followed by a bromination/desilicobromination reaction provides a simple and effective synthetic approach to a wide range of bromofluoroalkenes (up to >97/3). In addition, the bromofluoroalkenes can be used in Pd-catalyzed transformations giving access to both tri- and tetrasubstituted fluoroalkenes.
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