Journal
ORGANIC LETTERS
Volume 10, Issue 21, Pages 4751-4754Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801698k
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Funding
- CNRS-DFG
- Fundacion Ramon Areces
- [ANR-06-PCVI-0014]
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Two synthetic routes to Janus-type dendrimers possessing ammonium groups on one side and fluorescent dansyl derivatives on the other side are described. These surface-block dendrimers are obtained by the coupling of two different dendrons, built from the hexafunctional cyclotriphosphazene core. Their characterization and their photophysical behavior are reported. The largest compound possesses 10 ammonium groups and 5 dansyl groups; it is potentially useful as a fluorescent label in materials science and biology.
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