Journal
ORGANIC LETTERS
Volume 10, Issue 17, Pages 3793-3796Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801471f
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Cross-coupling reactions between lipophilic terminal alkynes and aryl bromides can be catalyzed by ligated Pd, in the absence of copper, in pure water at ambient temperatures. Small amounts of the nonionic amphiphile PTS assist by virtue of nanometer micelles formed spontaneously in an aqueous medium.
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