Journal
ORGANIC LETTERS
Volume 10, Issue 10, Pages 1931-1934Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800436u
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- NIGMS NIH HHS [GM36238] Funding Source: Medline
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Bacteriochlorins absorb strongly in the near-infrared spectral region and hence are ideally suited for diverse photomedical applications, yet naturally occurring bacteriochlorins have limited stability and synthetic malleability. A de novo route has been exploited to prepare synthetic bacteriochlorins that bear a geminal dimethyl group in each pyrroline ring for stability and a symmetrically branched 1,5-dimethoxypentyl group attached to each pyrrole ring for solubility in lipophilic media.
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