4.8 Article

Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters

Journal

ORGANIC LETTERS
Volume 10, Issue 13, Pages 2697-2700

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol800829q

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The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO(2) to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.

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