Journal
ORGANIC LETTERS
Volume 10, Issue 5, Pages 1025-1028Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800092p
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A combination of gold(l) complexes and amine bases catalyzes the 5-exo-dig cyclization of formyl alkynes. This direct alpha-functionalization of aldehydes with unactivated alkynes does not involve the use of preformed enol equivalents.
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