Journal
ORGANIC LETTERS
Volume 10, Issue 14, Pages 3165-3167Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8011869
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A brief synthesis of manzacidin C based on a chiral silane-promoted diastereo- and enatioselective acylhydrazone-alkene [3 + 2] cycloaddition reaction has been achieved. This synthesis is the first synthesis of any of the manzacidins wherein the C(4) and C(6) stereocenters are established in a single highly stereoselective step.
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