Journal
ORGANIC LETTERS
Volume 10, Issue 10, Pages 2071-2074Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800591u
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Using Pd(CF3CO2)(2)/(SS)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).
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