Journal
ORGANIC LETTERS
Volume 10, Issue 11, Pages 2315-2318Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800747v
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An efficient method for the catalytic asymmetric conjugate addition of diorganozinc reagents to vinyl sulfones is reported. Using a Binap circle Cu complex, enantioselectivities up to 98% ee and high yields can be attained for a variety of substrates. Several dialkylzinc reagents are also compatible with this procedure.
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