Journal
ORGANIC LETTERS
Volume 10, Issue 2, Pages 289-292Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702689v
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A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, (BDP)CuH smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand ratios typically on the order of 1000-10000:1 can be used leading to products in high yields.
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