Journal
ORGANIC LETTERS
Volume 10, Issue 21, Pages 4995-4998Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802071n
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Funding
- Ministerio de Ciencia e Innovacion [CTQ2005-08016, CSD2006-0003]
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Combining the advantages of homogeneous and heterogeneous enantioselective catalysis is possible through self-supported copper coordination polymers, based on a new kind of ditopic chiral ligand bearing two azabis(oxazoline) moieties. When the coordination polymer is used to catalyze a cyclopropanation reaction, it becomes soluble in reaction conditions but precipitates after reaction completion, allowing easy recovery and efficient reuse in the same reaction up to 14 times.
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