4.8 Article

Folding of long-chain alkanediammonium ions promoted by a cucurbituril derivative

Journal

ORGANIC LETTERS
Volume 10, Issue 12, Pages 2577-2580

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol800893n

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We report the isolation and characterization of two top-bottom differentiated CB[n]-type receptors, namely ns-CB[6] and cucurbituril derivative 2, which display diastereoselective recognition toward unsymmetrical guests. Compound 2 also promotes the back-folding of long chain alkanediammonium ions in water.

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