Journal
ORGANIC LETTERS
Volume 10, Issue 5, Pages 913-916Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol7030608
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Bis-phosphoryl-bridged stilbenes have been synthesized using an intramolecular cascade cyclization. They show intense blue fluorescences at longer wavelengths with higher quantum yields compared to those of the known element-bridged stilbenes. In addition, they have much lower reduction potentials due to the inductive effect of phosphoryl groups. The incorporation of the phosphoryl moiety is an effective way for the construction of highly electron-accepting pi-conjugated systems.
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