Journal
ORGANIC LETTERS
Volume 10, Issue 19, Pages 4267-4270Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801666w
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Funding
- European Commission for a Marie Curie Fellowship [MEIF-CT-2006-039981]
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An efficient nitro-Mannich/lactamization cascade of gamma-nitro esters with cyclic imines for the preparation of architecturally complex multicyclic piperidinone ring-containing structures has been developed. The reaction is broad in scope and stereoselective and may be coupled to an enantioselective nitroolefin Michael addition reaction as part of a highly enantio- and diastereoselective multicomponent process.
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