4.8 Article

Chromium(0)-Promoted [6π+2π] Cycloadditions of Allenes with Cycloheptatriene

Journal

ORGANIC LETTERS
Volume 10, Issue 24, Pages 5609-5612

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol802401a

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Funding

  1. National Institutes of Health [GM-30771]

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Photoinitiated [6 pi + 2 pi] cycloadditions of allenes with (eta(6)-cycloheptatriene)tricarbonylchromium(0) (1) are described. An example of asymmetric induction obtained by reaction of 1 with a chiral 1,3-disubstituted allene is also reported.

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