Journal
ORGANIC LETTERS
Volume 10, Issue 7, Pages 1413-1415Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800141t
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- Engineering and Physical Sciences Research Council [EP/C011074/2] Funding Source: researchfish
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A catalyst generated from Pd(dba)(2) and the bulky electron-rich phosphine ligand 2-(dicyclohexylphosphino)-2',4', 6'-tri-i-propyl-1 - 1'-biphenyl is effective for the alpha-arylation of oxindoles. Generation of the potassium-enolates of a range of oxindoles allows coupling with aryl chlorides, bromides, and triflates. Significant variation of the substitution pattern on both the oxindole and aryl halide is possible.
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