Journal
ORGANIC LETTERS
Volume 10, Issue 7, Pages 1501-1504Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800318h
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Diphenyl vinyl sulfonium salt and chiral amido-ketones undergo highly diaslereoselective epoxy-annulation reactions in good yield. The use of a chiral vinyl sulfonium salt dominates the stereochemical outcome of the annulation reaction (reagent control is greater than substrate control), and this has allowed the kinetic resolution of racemic amido-ketones to be achieved.
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