Journal
ORGANIC LETTERS
Volume 10, Issue 15, Pages 3307-3310Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8003468
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Expedient, facile syntheses of highly fluorinated benzobisbenzothiophenes (BBBT) are reported. Defined peripheral arrangements of sulfur and fluorine atoms lead to extensive crystalline networks of edge-to-edge S-F close contacts. The effects of various substitution patterns on self-assembly and electronic properties are described.
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