4.8 Article

Direct and stereoselective synthesis of α-linked 2-deoxyglycosides

Journal

ORGANIC LETTERS
Volume 10, Issue 19, Pages 4367-4370

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol801833n

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Funding

  1. NIH [NIGM 2R01GM065248]

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alpha-Linked 2-deoxyglycosides were conveniently obtained by employing a glycosyl donor having a participating (S)-(phenylthlomethyl)benzyl moiety at C-6, whereas 2,6-dideoxy-alpha-glycosides could be prepared by BF3 center dot Et2O-promoted activation of allyl glycosyl donors.

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