Journal
ORGANIC LETTERS
Volume 10, Issue 11, Pages 2107-2110Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800648d
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Funding
- NIGMS NIH HHS [R15 GM077170-01, GM077170, R15 GM077170] Funding Source: Medline
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Recently, we discovered a novel method for superarming glycosyl donors. Herein, this concept has been exemplified in one-pot oligosaccharide syntheses, whereby the superarmed glycosyl donor was chemoselectively activated over traditional armed and disarmed glycosyl acceptors. Direct side-by-side comparison of the reactivities of the classic armed and superarmed glycosyl donors further validates the credibility of the novel concept.
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