Journal
ORGANIC LETTERS
Volume 10, Issue 18, Pages 4089-4092Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8016275
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- Jacobs University
- Fonds der Chemischen Industrie
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The derivatization of 3-amino-9-ethylcarbazole with a diamino-alkyl anchor affords a fluorescent dye suitable for indicator displacement from cucurbituril macrocycles. The novel compound 1 shows, due to a complexation-induced pK(a) shift, a large and predictable dual fluorescence response (100-fold increase at 375 nm and 9-fold decrease at 458 nm) upon supramolecular encapsulation and a strong affinity for cation-receptor macrocycles, in particular cucurbit[6]uril (06). A direct application is presented by monitoring the enzymatic activity of lysine decarboxylase.
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