Journal
ORGANIC LETTERS
Volume 10, Issue 21, Pages 4887-4889Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801844w
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Funding
- Mizuho Foundation for the Promotion of Sciences and the Ministry of Education, Culture, Sports, Science and Technology of Japan [18032040, 20750078]
- Grants-in-Aid for Scientific Research [20750078, 18032040] Funding Source: KAKEN
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A palladium(0)/monophosphine catalyst promotes a cyclization reaction of 2-(alkynyl)aryl isocyanates with organoboron reagents to produce stereodefined 3-alkylideneoxindoles. The alkynyl and isocyanato groups undergo oxidative cyclization with Pd(0) to form an oxapalladacycle intermediate. Subsequent transmetalation and reductive elimination afford the product.
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