Journal
ORGANIC LETTERS
Volume 10, Issue 12, Pages 2389-2392Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800816f
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An efficient new route to prepare stereoselectively terminal conjugated dienes by coupling Grignard reagents and dienol phosphates in the presence of Fe(aCaC)(3) is described. The synthetic utility of this new iron-catalyzed procedure is illustrated by the synthesis of the pheromone of Diparopsis castanea according to a very expeditious strategy.
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