Journal
ORGANIC LETTERS
Volume 10, Issue 23, Pages 5473-5476Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol802295b
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Funding
- Institut de Chimie des Substances Naturelles
- COST Action D40 Innovative Catalysis: New Processes and Selectivities
- COST
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The preparation of optically active sulfilimines via the catalytic diastereoselective imination of sulfides using a chiral nitrene is described. Excellent yields up to 97% and good diastereoselectivities up to 96% have been obtained. Oxidation of the sulfilimines then stereospecifically affords the corresponding sulfoximines with very good yields in the 88-96% range.
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