Journal
ORGANIC LETTERS
Volume 10, Issue 22, Pages 5183-5186Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8021484
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Funding
- Encouragement of Young Scientists
- Japan Society for the Promotion of Science (JSPS)
- Research Foundation for Pharmaceutical Sciences
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Studies about the regiocontrolled addition of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and base. Contrary to the formation of endo-olefinic products in the reactions using hydroxopalladium complex, predominant production of exo-olefinic products was observed by the reaction with hydroxoplatinum complex.
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