Journal
ORGANIC LETTERS
Volume 10, Issue 10, Pages 2043-2046Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800515w
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A concise synthesis of maremycins A and D-1 has been accomplished via cycloaddition of a chiral cyclic nitrone with (E)-3-ethylidene-1-methylindolin-2-one as a key step. This synthesis clarifies the stereochemistry of the maremycins and is suitable for large-scale synthesis for biological screening.
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