4.8 Article

Synthesis of 5-vinylideneoxazolidin-2-ones by DBU-mediated CO2-fixation reaction of 4-(benzylamino)-2-butynyl carbonates and benzoates

Journal

ORGANIC LETTERS
Volume 10, Issue 10, Pages 2083-2086

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol800663v

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A CO2-fixation reaction of 4-(benzylamino)-2-butynyl carbonates and benzoates, carried out in the presence of DBU, provides substituted 5-vinylideneoxazolidin-2-ones. The reaction has been successfully applied to the CO2-recycling process and fixation of atmospheric CO2.

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