Journal
ORGANIC LETTERS
Volume 10, Issue 5, Pages 693-696Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol703058p
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Catalytic Sommelet-Hauser rearrangement is reported. The Rh(II)-catalyzed reaction of aryldiazoacetates with ethyl benzylthioacetate affords Sommelet-Hauser rearrangement products in good to excellent yields. This reaction provides a reliable and efficient way to introduce a substituent to the ortho position of arylacetates.
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