Journal
ORGANIC LETTERS
Volume 10, Issue 20, Pages 4609-4612Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801936j
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- Japan Science and Technology Agency (JST)
- MEXT
- JSPS
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A Pd(II) catalyst for the hydroarylation of fullerene with boronic acids is presented. Treatment of C-60 with an arylboronic acid in the presence of a catalytic amount of Pd(2-PyCH=NPh)(OCOC6F5)(2) in H2O/1,2-Cl2C6H4 at room temperature furnishes the hydroarylation product (Ar-C-60-H) in good yield with high selectivity. This complex possesses high catalytic activity paired with bench stability in the solid state.
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