Journal
ORGANIC LETTERS
Volume 10, Issue 20, Pages 4585-4588Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801864c
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Funding
- Ministry of Education in Singapore [ARC12/07, T206133225]
- Nanyang Technological University [RG53/07, RG140/06]
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A facile stereoselective synthesis of multifunctionalized tetrahydro-1,2-oxazines (THOs) has been achieved by the organocatalyzed asymmetric tandem alpha-aminoxylation/aza-Michael reaction for the C-O/C-N bond formations in moderate to good yields with excellent diastereo- (>99:1 dr) and enantioselectivities (92% to >99% ee).
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