Journal
ORGANIC LETTERS
Volume 10, Issue 5, Pages 873-876Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol7030125
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A convenient, highly efficient, decatungstate-mediated chemical methodology to functionalize fullerenes is demonstrated. A variety of radicals have been generated by the photochemical interaction of tetrabutylammonium decatungstate [(n-Bu4N)(4)W10O32] and para-substituted toluenes, anisoles, and thioanisole and effectively trapped by the [60]fullerene affording the corresponding 1,2-dihydro[60]fullerene monoadducts in moderate to good yields.
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