Journal
ORGANIC LETTERS
Volume 10, Issue 17, Pages 3765-3768Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801419m
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Funding
- National Natural Science Foundation of China [30725049, 30623008]
- Hi-Tech Program [2006AA09Z442]
- Shanghai Commission of Science and Technology [05DZ19331]
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The first total synthesis of the originally proposed and revised structure of scleritodermin A, along with an isomer, were achieved by the use of an alpha-azido carboxyl group serving as the key alpha-ketoamide precursor, thus leading to a revision of the structure originally proposed for natural scleritodermin A.
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