Journal
ORGANIC LETTERS
Volume 10, Issue 18, Pages 4061-4064Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801601q
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- National Science Council, Taiwan
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We report a one-pot synthesis of benzopyrones and tricyclic spiroketones from hydrative carbocyclization of oxodiyne substrates catalyzed by PtCl(2) and PPh(3)AuCl/AgOTf, respectively. The distinct carbocyclizations with Pt and Au catalysts stem from their altered regioselectivity in the oxo-assisted hydration of the neighboring alkyne carbons.
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