Journal
ORGANIC LETTERS
Volume 10, Issue 10, Pages 2007-2010Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800620s
Keywords
-
Categories
Ask authors/readers for more resources
In our attempts of tuning the molecular packing of tetracene with H-bonding, we found that tetracenediamide was much more vulnerable to photooxidation than tetracene in crystals despite their similar sensitivity to photooxidation in solution. Unexpectedly photooxidation of tetracenediamide in solution and in crystals show different regioselectivities. To explain the regioselectivity, a mechanism involving H-bonding is proposed. This study indicates that molecular packing in solid state can play an important role in solid-gas reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available