Journal
ORGANIC LETTERS
Volume 10, Issue 9, Pages 1843-1845Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8004479
Keywords
-
Categories
Ask authors/readers for more resources
Treatment of 1-bromo-2,2-dichloro-3-trimethylsilylcyclopropane with CsF in THF refluxing temperature gave chlorocyclopropenyl cation (1), which reacted with various nucleophiles to generate 3-monosubstituted 1-chlorocyclopropenes. The Diels - Alder reactions of 3-monosubstituted 1-chlorocyclopropenes with 1,3-diphenylisobenzofuran (DPIBF) yielded only the exo-anti adducts in excellent yield. When cation 1 was treated with water and trapped with DPIBF, an aldehyde, 12, was isolated.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available