4.8 Article

Silaborations of 1,3-enynes -: Substrate controlled allene/1,3-diene selectively

Journal

ORGANIC LETTERS
Volume 10, Issue 12, Pages 2505-2508

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol800768x

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Silaboration of 1,3-enynes catalyzed by group 10 metal complexes affords 1,3-dienes with vinylborane and vinylsilane functions or 1,2-dienes with allylborane and vinylsilane functions. The type of product formed is determined by the size of the alkyne substituent.

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