Journal
ORGANIC LETTERS
Volume 10, Issue 4, Pages 617-620Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol702980p
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An indene-based thiazolidinethione chiral auxiliary was prepared in two steps from trans-1-amino-2-indanol. Chlorotitanium enolates of this chiral auxiliary delivered excellent diastereoselectivities in propionate and acetate aldol additions. The chiral auxiliary was easily removed to deliver several valuable functionalities.
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