4.8 Article

Palladium-Catalyzed Hiyama Cross-Coupling Reactions of Aryl Mesylates

Journal

ORGANIC LETTERS
Volume 10, Issue 21, Pages 4971-4974

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol802049t

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Funding

  1. National Natural Science Foundation of China [20772018]
  2. Shanghai Pujiang Program
  3. Program for New Century Excellent Talents in University [NCET-07-0208]

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The combination of palladium acetate with XPhos shows high efficiency in the Hiyama cross-coupling reactions of aryl mesylates with arylsilanes. The reactions proceed smoothly to generate the corresponding biaryl compounds in good yields.

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