Journal
ORGANIC LETTERS
Volume 10, Issue 11, Pages 2287-2290Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800701j
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- NCRR NIH HHS [P20 RR016470] Funding Source: Medline
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Herein we describe the construction of hexadecameric self-assembled dendrimers (SADs) using a series of dendronized 8-(m-acetylphenyl)2'-deoxyguanosine (mAG) subunits. The azido-substituted mAG subunits were covalently linked to alkynyl polyester dendrons using a copper-catalyzed 1,3-dipolar cycloaddition reaction. Discrete SADs are formed with high fidelity and thermal stability even with the increased steric hindrance offered by the dendrons.
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