Journal
ORGANIC LETTERS
Volume 10, Issue 6, Pages 1251-1254Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol800143b
Keywords
-
Categories
Ask authors/readers for more resources
The reaction of [60]fullerene with an, arylzinc halide in a mixture of THF and DMF produces a mono(2-tetrahydrofuranyl) adduct of [60]fullerene C-60(C4H7O)H instead of the expected arylated fullerene. The reaction involves a C-H bond activation at the 2-position of THF that probably takes place through a radical mechanism. In the presence of a copper(I) complex, the reaction does not stop at the stage of mono-addition, with the aryl group of the zinc reagent adding four times regioselectively to the mono(2-tetrahydrofuranyl) adduct to produce a penta-adduct C60Ar4(C4H7O)H. This product can be converted further to the corresponding buckyferrocene Fe[C60Ar4(C4H7O)]Cp and its derivatives.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available