Journal
ORGANIC LETTERS
Volume 10, Issue 23, Pages 5397-5400Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8022775
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Funding
- Skaggs Institute
- National Institutes of Health [GM27932]
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A deep, self-folding cavitand responds to minor electronic differences between suitably sized adamantane guests. Binding constants range from < 0.5 to 4000 M-1 for guests as similar as 1-bromoadamantane and 1-cyanoadamantane. The barriers to guest exchange also vary up to 3 kcal mol(-1).
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