Journal
ORGANIC LETTERS
Volume 10, Issue 17, Pages 3891-3894Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801431z
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Funding
- Fonds der Chemischen Industrie
- DFG
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The aryl sulfoxide moiety (ArSO) allows an expedient two-step meta-, para-difunctionalization of readily available diaryl sulfoxides. In the first step, the sulfoxide plays the role of a directing metalation group. In the second step, triggered by i-PrMgCl-LiCl, it becomes a leaving group and undergoes a regioselective sulfoxide-magnesium exchange.
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