Journal
ORGANIC LETTERS
Volume 10, Issue 17, Pages 3829-3832Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol801534e
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19027005]
- Japan Society for the Promotion of Science (JSPS) [19390001]
- Akiyama Foundation
- Grants-in-Aid for Scientific Research [19027005] Funding Source: KAKEN
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A new method for preparation of functionalized enamides by a nickel-catalyzed multicomponent coupling of ynamides, aldehydes, and silane has been developed. The coupling reaction proceeded in the presence of a nickel-IMes catalyst to give the corresponding gamma-silyloxyenamide derivative, which has an allylic alcohol moiety in the molecule, in a highly stereoselective manner.
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