Journal
ORGANIC LETTERS
Volume 10, Issue 14, Pages 2975-2978Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol8006887
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The reaction of 2-(chloromethyl)phenylboronic acid (1) with alkynes in the presence of a Rh(I) complex gave indene derivatives in high yields. The regioselectivity depends on the steric nature of the substituent on the alkynes. A bulky group favors the alpha-position of indenes.
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