Journal
ORGANIC ELECTRONICS
Volume 13, Issue 1, Pages 195-198Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2011.10.019
Keywords
External heavy atom effect; Triplet; Singlet; Iodide; Organic light-emitting device
Funding
- NSFC [61177020, 10934001, 60907015, 10821062]
- National Basic Research Program of China [2007CB307000, 2009CB930504]
- Beijing Municipal Science and Technology Project [Z10110305041 0002]
- Grants-in-Aid for Scientific Research [22560013] Funding Source: KAKEN
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An unusual heavy atom effect has been identified in an organic light emitting device (OLED) containing polyvinylcarbazole (PVK) as the host, the red fluorescent dye 2-{2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-yl)-vinyl]-pyran-4-ylidene}-malononitrile (DCM2) as the emitter, and non-emitting 1,8-diiodooctane (RI) as a heavy atom source instead of a rare metal. The intensity of electroluminescence (EL) of DCM2 changes with the concentration of RI, with a maximum EL intensity obtained for DCM2 at a concentration of 0.25% of RI. Photoluminescence (PL) spectra of PVK-DCM2 films show increased singlet emission from DCM2 in the presence of iodide at 12 K. The enhanced fluorescence induced by iodide is caused by energy transfer from both the singlet and triplet states of PVK to the singlet states of DCM2. These results suggest an alternative way to use the triplet energy of fluorescent materials with external heavy atoms rather than conventional phosphorescent dyes containing rare heavy metal atoms. (C) 2011 Elsevier B.V. All rights reserved.
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