Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 41, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob01754a
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Funding
- Council of Scientific and Industrial Research, New Delhi
- Science and Engineering Research Board, DST, India [SR/FT/CS-157/2011, EMR/2016/000988]
- Indian Association for the Cultivation of Science, New Delhi
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Stereoselective synthesis of common C-1-C-19 skeletons of pentane macrolides strevertenes A and G possessing 10 stereogenic centers has been achieved using a flexible and convergent strategy. The salient features of this synthetic study include the Evans aldol reaction for the constructions of C-2, C-3, C-13, and C-14 centers, CBS reduction for the generation of a C-7 center, Hoveyda-Grubbs cross olefin metathesis for the synthesis of C-8-C-9 bond, and Wittig olefination for the installation of C-16-C-19 conjugated olefins.
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