4.6 Article

A convenient tandem one-pot synthesis of donor-acceptor-type triphenylene 2,3-dicarboxylic esters from diarylacetylene

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 36, Pages 6977-6981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01503g

Keywords

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Funding

  1. National Natural Science Foundation of China [21072140, 21202109, 51273133]
  2. Sichuan Province Higher Education System Key Laboratory of Advanced Functional Materials [KFKT2012-02]
  3. Key Growth Foundation [14py01]
  4. Outstanding (Postgraduate) Dissertation Growth Foundation [xyz2014-[7]-31]
  5. Special Funds for Sharing Large Precision Equipment at the Sichuan Normal University [DJ2014-23, DJ2014-24]

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A tandem one-pot method for the direct synthesis of polysubstituted triphenylene 2,3-dicarboxylic esters with different substitution patterns was developed by enyne metathesis of diarylacetylene, followed by Diels-Alder, aromatization and a cyclization cascade.

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