Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 31, Pages 5847-5855Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00733f
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Funding
- MEXT (Japan) [24105523, 26105743]
- Grants-in-Aid for Scientific Research [26105743, 24105523] Funding Source: KAKEN
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A highly diastereosetective and enantioselective method for the asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones using the Michael addition reaction of malonates under catalysis with the primary amine-thiourea conjugate catalyst and PPY at high pressure was developed.
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