Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 11, Pages 1717-1720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob00009a
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Substrate association and asymmetric induction in oxazaborolidinium-catalyzed cycloadditions of maleimides are shown to depend strongly on the catalyst's aromatic substituents. Favourable dispersive forces bias complexation to the catalyst's convex (exo) face exposing a single diastereoface of the substrate preferentially.
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