Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 12, Issue 2, Pages 251-254Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ob42007h
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Funding
- National Science Foundation of China [21102123, 21372188]
- Hunan Province Department of Education [11C1208]
- Xiangtan University [10QDZ36, 10XZX10]
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A rhodium-catalyzed intermolecular hydroarylation of internal alkynes with N-1-phenylbenzotriazoles via C-H bond activation is described. This transformation offers an alternative method for the hydroarylation of internal alkynes with high stereoselectivity. The reaction mechanism was discussed according to the deuterium-labeling experiments.
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